Artigo de periodico

A promising sustainable PHB-ZnO composite for development of biodegradable filaments (2021)

• Authors:
  • Silva, Nycolle G. S.
  • Zanini, Noelle C
  • Barbosa, Rennan F. S
  • Souza, Alana G.
  • Medeiros, Simone de Fátima
  • Rosa, Derval dos Santos
  • Mulinari, Daniella Regina
• Autor USP: SAMPAIO, SIMONE DE FÁTIMA MEDEIROS - EEL
• Unidade: EEL
• DOI: 10.1002/pc.26363
• Assunto: IMPRESSÃO 3-D
• Keywords: 3D-printing; biodegradable 3D filament; poly(3-hydroxybutyrate); ZnO particles
• Agências de fomento:
  • Financiamento FAPESP
  • Financiamento CNPq
  • Financiamento CAPES
  • Financiamento FAPERJ
• Language: Inglês
• Abstract: The development of new biodegradable composites with superior properties isan attractive approach to develop environmentally friendly materials with newpotential applications. In this work, we prepared and characterized PHB fila-ments with different concentrations of ZnO particles (from 0.5 up to 16 wt%)to evaluate this mixture's effect on the physico-chemical, thermal properties,and morphological biofilament characteristics. The FTIR and Raman resultsindicated a possible chemical interaction between the ZnO and PHB, alteringthe helical polymeric and crystalline structure. The ZnO particles increasedthe composites' thermal stability, mainly at higher filler contents, confirmedby Tonset and the thermal resistance index, associated with the interfacebetween the particles and the PHB matrix. Also, DSC results indicated thathigher ZnO contents increased the PHB amorphous characteristic, which facil-itates its use as filaments. The microscopies allowed the evaluation of compos-ites' morphology and indicated good filler dispersion and homogeneity, andthe filament diameters were adequate to the FDM 3D printing technique.SEM-EDS confirmed ZnO presence at filament structure, which probably sta-bilized the PHB matrix during the extrusion process and allowed the printingprocess for the PHB-0.5%ZnO filaments into scaffolds, showing the potentialapplication in additive manufacturing processes. These findings may expandPHB applications combining ZnO properties to develop functional and activematerials for biomedical and packaging applications.
• Imprenta:
  • Publisher: SPE
  • Publisher place: Danbury-NY
  • Date published: 2021
• Source:
  • Título: Polymer composites
  • ISSN: 1548-0569
  • Volume/Número/Paginação/Ano: v.43, p.144-159, 2021

Informações sobre o DOI: 10.1002/pc.26363 (Fonte: oaDOI API)
• Este periódico é de assinatura
• Este artigo NÃO é de acesso aberto
  
• Cor do Acesso Aberto: closed

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How to cite

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• ABNT

  SILVA, Nycolle G. S. et al. A promising sustainable PHB-ZnO composite for development of biodegradable filaments. Polymer composites, v. 43, p. 144-159, 2021Tradução . . Disponível em: https://doi.org/10.1002/pc.26363. Acesso em: 30 dez. 2025.

• APA

  Silva, N. G. S., Zanini, N. C., Barbosa, R. F. S., Souza, A. G., Medeiros, S. de F., Rosa, D. dos S., & Mulinari, D. R. (2021). A promising sustainable PHB-ZnO composite for development of biodegradable filaments. Polymer composites, 43, 144-159. doi:10.1002/pc.26363

• NLM

  Silva NGS, Zanini NC, Barbosa RFS, Souza AG, Medeiros S de F, Rosa D dos S, Mulinari DR. A promising sustainable PHB-ZnO composite for development of biodegradable filaments [Internet]. Polymer composites. 2021 ;43 144-159.[citado 2025 dez. 30 ] Available from: https://doi.org/10.1002/pc.26363

• Vancouver

  Silva NGS, Zanini NC, Barbosa RFS, Souza AG, Medeiros S de F, Rosa D dos S, Mulinari DR. A promising sustainable PHB-ZnO composite for development of biodegradable filaments [Internet]. Polymer composites. 2021 ;43 144-159.[citado 2025 dez. 30 ] Available from: https://doi.org/10.1002/pc.26363

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