Artigo de periodico

Production of 5-Hydroxymethylfurfural from Direct Conversion of Cellulose Using Heteropolyacid/Nb2O5 as Catalyst (2020)

• Authors:
  • Nogueira, Jéssica Siqueira Mancilha
  • Santana, Vinicius Tomaz
  • Henrique, Paulo Vitor
  • Aguiar, Leandro Gonçalves de
  • Silva, João Paulo Alves
  • Mussatto, Solange I
  • Carneiro, Livia Melo
• USP affiliated authors: AGUIAR, LEANDRO GONÇALVES DE - EEL ; SILVA, JOÃO PAULO ALVES - EEL ; CARNEIRO, LIVIA MELO - EEL ; SANTANA, VINÍCIUS TOMAZ - EEL ; NOGUEIRA, JÉSSICA SIQUEIRA MANCILHA MUNIZ TOLEDO - EEL ; HENRIQUE, PAULO VITOR - EEL
• Unidade: EEL
• DOI: 10.3390/catal10121417
• Subjects: CINÉTICA; CELULOSE
• Keywords: 5-hydroxymethylfurfural; cellulose; optimization; heteropolyacid catalyst; kinetic
• Agências de fomento:
  • Financiamento CAPES
  • Financiamento FAPESP
  • Financiamento Novo Nordisk Foundation
  • Financiamento CNPq
• Language: Inglês
• Abstract: This study aimed to select the best reaction conditions to produce 5-hydroxymethylfurfural (HMF) from cellulose using heterogeneous catalyst based on a heteropolyacid (H3PW12O40—HPW) and Nb2O5. Initially, the influence of the temperature (160 or 200 ◦C), acetone:water ratio (50:50 or 75:25 v/v), cellulose load (5% or 10% w/v) and catalyst concentration (1% or 5% w/v) on HMF production from cellulose was evaluated through a Taguchi’s L16 screening experimental design. Afterwards, the main variables affecting this process, namely the temperature (160–240 ◦C) and acetone:water ratio (60:40–90:10 v/v), were optimized using a central composite rotatable design. Next, a kinetic study on HMF production from cellulose was carried out. Finally, HMF production from cellulose obtained from different biomass sources was evaluated. It was found that the reaction conditions able to result in maximum HMF yield, i.e., around 20%, were 200 ◦C, acetone:water ratio of 75:25 (v/v), 10% w/v of cellulose, and 5% w/v of catalyst concentration. The kinetic study revealed that the Langmuir–Hinshelwood–Hougen–Watson approach fit to the experimental data. Under the optimized conditions, the catalyst HPW/Nb2O5 was also effective in converting different sources of cellulose into HMF.
• Imprenta:
  • Publisher: MDPI
  • Publisher place: Basel
  • Date published: 2020
• Source:
  • Título: Catalysts
  • ISSN: 2073-4344
  • Volume/Número/Paginação/Ano: v. 10, n. 12, p. 1-23, 2020

Informações sobre o DOI: 10.3390/catal10121417 (Fonte: oaDOI API)
• Este periódico é de acesso aberto
• Este artigo é de acesso aberto
• URL de acesso aberto
• Cor do Acesso Aberto: gold
• Licença: cc-by

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How to cite

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• ABNT

  NOGUEIRA, Jéssica Siqueira Mancilha et al. Production of 5-Hydroxymethylfurfural from Direct Conversion of Cellulose Using Heteropolyacid/Nb2O5 as Catalyst. Catalysts, v. 10, n. 12, p. 1-23, 2020Tradução . . Disponível em: https://doi.org/10.3390/catal10121417. Acesso em: 28 dez. 2025.

• APA

  Nogueira, J. S. M., Santana, V. T., Henrique, P. V., Aguiar, L. G. de, Silva, J. P. A., Mussatto, S. I., & Carneiro, L. M. (2020). Production of 5-Hydroxymethylfurfural from Direct Conversion of Cellulose Using Heteropolyacid/Nb2O5 as Catalyst. Catalysts, 10( 12), 1-23. doi:10.3390/catal10121417

• NLM

  Nogueira JSM, Santana VT, Henrique PV, Aguiar LG de, Silva JPA, Mussatto SI, Carneiro LM. Production of 5-Hydroxymethylfurfural from Direct Conversion of Cellulose Using Heteropolyacid/Nb2O5 as Catalyst [Internet]. Catalysts. 2020 ; 10( 12): 1-23.[citado 2025 dez. 28 ] Available from: https://doi.org/10.3390/catal10121417

• Vancouver

  Nogueira JSM, Santana VT, Henrique PV, Aguiar LG de, Silva JPA, Mussatto SI, Carneiro LM. Production of 5-Hydroxymethylfurfural from Direct Conversion of Cellulose Using Heteropolyacid/Nb2O5 as Catalyst [Internet]. Catalysts. 2020 ; 10( 12): 1-23.[citado 2025 dez. 28 ] Available from: https://doi.org/10.3390/catal10121417

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