Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose (2020)
- Authors:
- USP affiliated authors: SILVA, JOÃO PAULO ALVES - EEL ; CARNEIRO, LIVIA MELO - EEL ; NOGUEIRA, JÉSSICA SIQUEIRA MANCILHA MUNIZ TOLEDO - EEL
- Unidade: EEL
- DOI: 10.3390/en13030655
- Assunto: ENGENHARIA QUÍMICA
- Keywords: 5-hydroxymethylfurfural; glucose; heteropolyacid catalysts
- Agências de fomento:
- Language: Inglês
- Abstract: This study aimed to evaluate the synthesis and application of heterogeneous catalysts based on heteropolyacids for 5-hydroxymethylfurfural (HMF) production from glucose. Initially, assays were carried out in order to establish the most favorable catalyst synthesis conditions. For such purpose, calcination temperature (300 or 500 °C), type of support (Nb2O5 or Al2O3), and active phase (H3PW12O40—HPW or H3PMo12O40—HPMo) were tested and combined based on Taguchi’s L8 orthogonal array. As a result, HPW-Nb2O5 calcined at 300 °C was selected as it presented optimal HMF production performance (9.5% yield). Subsequently, the reaction conditions capable of maximizing HMF production from glucose using the selected catalyst were established. In these experiments, different temperatures (160 or 200 °C), acetone-to-water ratios (1:1 or 3:1 v/v), glucose concentrations (50 or 100 g/L), and catalyst concentrations (1 or 5% w/v) were evaluated according to a Taguchi’s L16 experimental design. The conditions that resulted in the highest HMF yield (40.8%) consisted of using 50 g/L of glucose at 160 °C, 1:1 (v/v) acetone-to-water ratio, and catalyst concentration of 5% (w/v). Recycling tests revealed that the catalyst can be used in four runs, which results in the same HMF yield (approx. 40%).
- Imprenta:
- Publisher place: Basel, Suécia
- Date published: 2020
- Source:
- Status:
- Artigo publicado em periódico de acesso aberto (Gold Open Access)
- Versão do Documento:
- Versão publicada (Published version)
- Acessar versão aberta:
-
ABNT
NOGUEIRA, Jéssica Siqueira Mancilha et al. Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose. Energies, v. 13, n. 3 , p. 17, 2020Tradução . . Disponível em: https://doi.org/10.3390/en13030655. Acesso em: 02 abr. 2026. -
APA
Nogueira, J. S. M., SILVA, J. P. A., Mussatto, S. I., & CARNEIRO, L. M. (2020). Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose. Energies, 13( 3 ), 17. doi:10.3390/en13030655 -
NLM
Nogueira JSM, SILVA JPA, Mussatto SI, CARNEIRO LM. Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose [Internet]. Energies. 2020 ;13( 3 ): 17.[citado 2026 abr. 02 ] Available from: https://doi.org/10.3390/en13030655 -
Vancouver
Nogueira JSM, SILVA JPA, Mussatto SI, CARNEIRO LM. Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose [Internet]. Energies. 2020 ;13( 3 ): 17.[citado 2026 abr. 02 ] Available from: https://doi.org/10.3390/en13030655 - Synthesis and application of heterogeneous catalysts based on heteropolyacids for the production of 5-hydroxymethylfurfural from glucose
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