@article{articlec4082398, title = {A statistical definition of limit of detection for calibration-free laser-induced breakdown spectroscopy}, author = {Villas Boas, Paulino Ribeiro and Borduchi, Luís Carlos Leva}, year = {2023}, doi = {10.1016/j.sab.2023.106690}, journal = {Spectrochimica Acta B} }