The cationic polymerization of tung oil and its fatty-acid methyl ester (2020)
- Authors:
- Autor USP: LACERDA, TALITA MARTINS - EEL
- Unidade: EEL
- DOI: 10.1016/j.indcrop.2020.112886
- Assunto: BIOTECNOLOGIA
- Keywords: Tung oil; Methyl α-eleostearate; Tifluoroacetic acid; Cationic polymerization
- Agências de fomento:
- Language: Inglês
- Abstract: The use of renewable resources for the synthesis of macromolecular materials is a very promising strategy, which opens the way to the production of new polymers with a reduced environmental impact. Vegetable oils have been considered for this purpose for decades, with many well established commercial materials. Herein, tung oil and its major fatty acid methyl ester were submitted for the first time to cationic polymerization using trifluoroacetic acid as an initiator of moderate strength. While crude tung oil quickly polymerized to form crosslinked gel-like materials, the cationic polymers from methyl α-eleostearate remained soluble even when high concentrations of acid were used, thus allowing its progress to be followed by NMR spectroscopy. Besides gathering information on the properties of the isolated polymers, it was therefore possible to access some important mechanistical aspects related to both the cationic polymerization and the cyclization of the conjugated trienes borne by the tung oil backbone.
- Imprenta:
- Source:
- Título: Industrial crops and products
- ISSN: 0926-6690
- Volume/Número/Paginação/Ano: v.157, p.1-15 , art. n.112886-, 2020
- Este periódico é de assinatura
- Este artigo NÃO é de acesso aberto
- Cor do Acesso Aberto: closed
-
ABNT
LACERDA, Talita Martins e GANDINI, Alessandro. The cationic polymerization of tung oil and its fatty-acid methyl ester. Industrial crops and products, v. 157, n. art. 112886-, p. 1-15 , 2020Tradução . . Disponível em: https://doi.org/10.1016/j.indcrop.2020.112886. Acesso em: 29 dez. 2025. -
APA
Lacerda, T. M., & Gandini, A. (2020). The cationic polymerization of tung oil and its fatty-acid methyl ester. Industrial crops and products, 157( art. 112886-), 1-15 . doi:10.1016/j.indcrop.2020.112886 -
NLM
Lacerda TM, Gandini A. The cationic polymerization of tung oil and its fatty-acid methyl ester [Internet]. Industrial crops and products. 2020 ;157( art. 112886-): 1-15 .[citado 2025 dez. 29 ] Available from: https://doi.org/10.1016/j.indcrop.2020.112886 -
Vancouver
Lacerda TM, Gandini A. The cationic polymerization of tung oil and its fatty-acid methyl ester [Internet]. Industrial crops and products. 2020 ;157( art. 112886-): 1-15 .[citado 2025 dez. 29 ] Available from: https://doi.org/10.1016/j.indcrop.2020.112886 - Hidrólise de polpa de sisal como via de produção de etanol e materiais
- Monomers and Macromolecular Materials from Renewable Resources: State of the Art and Perspectives
- Furan Polymers: State of the Art and Perspectives
- The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources
- Hidrofobização de compósitos baseados em polissacarídeos microbianos
- Polymers from tung oil and methyl-α-eleostearate;-eleostearate via cationic mechanism
- Método de obtenção de polímeros e copolímeros a partir de adutos dieno-dienófilo bifuncionais
- Macromolecular materials based on the application of the Diels-Alder reaction to natural polymers and plant oils
- Cationic copolymerization of furfuryl alcohol and tung oil derivatives
- Copolymers of xylan-derived furfuryl alcohol and natural oligomeric tung oil derivatives
Informações sobre o DOI: 10.1016/j.indcrop.2020.112886 (Fonte: oaDOI API)
How to cite
A citação é gerada automaticamente e pode não estar totalmente de acordo com as normas
