Phase Equilibrium Involving Xylose, Water, and Ethylene Glycol or 1,2-Propylene Glycol at Different Temperatures (2019)
- Authors:
- Autor USP: CASTILLO, PEDRO FELIPE ARCE - EEL
- Unidade: EEL
- DOI: 10.1021/acs.jced.8b01128
- Subjects: ÁLCOOL; SOLUÇÕES; SOLUBILIDADE
- Keywords: Alcohols; Liquids; Mixtures; Solutions; Solubility
- Agências de fomento:
- Language: Inglês
- Abstract: Xylose is an important molecule that can be used in the production of chemicals such as ethylene glycol and 1,2-propylene glycol. Experimental and theoretical information are fundamental for the development of conversion and separation processes. For the supply of solubility data, this work sought to study solid–liquid equilibrium of xylose in binary liquid solutions formed by water/ethylene glycol and water/1,2-propylene glycol in the temperature range between 293.15 and 323.15 K, covering the entire molar composition range of the binary solution. The Jouyban–Acree and NRTL models were applied in the correlation of experimental data, and the UNIFAC and ASOG models were applied in the prediction of experimental data. Xylose showed solubility in the pure components following the order water > ethylene glycol > 1,2-propylene glycol. Intermediate values of solubility are related to intermediate concentrations of the binary liquid mixture. The mathematical models were successfully applied, and new parameters of UNIFAC and ASOG are presented.
- Imprenta:
- Publisher: ACS
- Publisher place: Washington-DC
- Date published: 2019
- Source:
- Título: Journal of chemical and engineering data
- ISSN: 0021-9568
- Volume/Número/Paginação/Ano: v.64, n.5, p.2163-2169, 2019
- Status:
- Artigo possui versão em acesso aberto em repositório (Green Open Access)
- Versão do Documento:
- Versão submetida (Pré-print)
- Acessar versão aberta:
-
ABNT
MACHADO, Patrícia G. et al. Phase Equilibrium Involving Xylose, Water, and Ethylene Glycol or 1,2-Propylene Glycol at Different Temperatures. Journal of chemical and engineering data, v. 64, n. 5, p. 2163-2169, 2019Tradução . . Disponível em: https://doi.org/10.1021/acs.jced.8b01128. Acesso em: 09 abr. 2026. -
APA
Machado, P. G., Galvão, A. C., Robazza, W. da S., Castillo, P. F. A., & Barbosa, L. V. (2019). Phase Equilibrium Involving Xylose, Water, and Ethylene Glycol or 1,2-Propylene Glycol at Different Temperatures. Journal of chemical and engineering data, 64( 5), 2163-2169. doi:10.1021/acs.jced.8b01128 -
NLM
Machado PG, Galvão AC, Robazza W da S, Castillo PFA, Barbosa LV. Phase Equilibrium Involving Xylose, Water, and Ethylene Glycol or 1,2-Propylene Glycol at Different Temperatures [Internet]. Journal of chemical and engineering data. 2019 ;64( 5): 2163-2169.[citado 2026 abr. 09 ] Available from: https://doi.org/10.1021/acs.jced.8b01128 -
Vancouver
Machado PG, Galvão AC, Robazza W da S, Castillo PFA, Barbosa LV. Phase Equilibrium Involving Xylose, Water, and Ethylene Glycol or 1,2-Propylene Glycol at Different Temperatures [Internet]. Journal of chemical and engineering data. 2019 ;64( 5): 2163-2169.[citado 2026 abr. 09 ] Available from: https://doi.org/10.1021/acs.jced.8b01128 - Experimental Data and Thermodynamics Modeling (PC-SAFT EoS) of the {CO 2</sub> + Acetone + Pluronic F-127} System at High Pressures
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